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Polymerization of Isobutylene and the Copolymerization of Isobutylene and Isoprene Initiated by the Metallocene Derivative Cp*TiMe2(μ-Me)B(C6F5)3

✍ Scribed by Barsan, Florin; Karam, Arquimedes R.; Parent, Michelle A.; Baird, Michael C.

Book ID
111656195
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
255 KB
Volume
31
Category
Article
ISSN
0024-9297

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Polymerization of propylene by Cp\*TiMe 2 (-Me)B(C 6 F 5 ) 3 in the presence of increasing partial pressures of H 2 results in ever decreasing polymer molecular weights, which is consistent with the hydrogenolytic chain transfer processes involving metal-polymer bonds in many heterogeneous and homog

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Isobutene Polymerization and Copolymerization with Isoprene Initiated by [Cp*TiMe2]+ in the Presence of a Novel Type of Weakly Coordinating Counteranion
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## Abstract Summary: The highly electrophilic borane B(C~6~F~5~)~3~ reacts with octadecanoic acid (__n__‐C~17~H~35~CO~2~H, stearic acid) to form 1:1 and 2:1 adducts [__n__‐C~17~H~35~CO~2~H][B(C~6~F~5~)~3~] and [__n__‐C~17~H~35~CO~2~H][B(C~6~F~5~)~3~]~2~. These adducts exhibit enhanced acidities, an