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Polymerization of cyclohexene oxide with aluminum complex-silanol catalyst. IV. Photopolymerization with Ph3SiCOPh-Al complex-alcohol catalyst system

✍ Scribed by Hayase, S. ;Ito, T. ;Suzuki, S. ;Wada, M.


Book ID
105333910
Publisher
John Wiley and Sons
Year
1982
Weight
458 KB
Volume
20
Category
Article
ISSN
0360-6376

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Polymerization of cyclohexene oxide with
✍ Hayase, Shuzi ;Onishi, Yasunobu ;Suzuki, Shuichi ;Wada, Moriyasu 📂 Article 📅 1983 🏛 John Wiley and Sons ⚖ 574 KB

## Abstract The activity of an aluminum complex/polysilanol polymerization catalyst was examined in order to confirm the dependence of catalytic activation on silanol chain length. Tris (acetylacetonato)–aluminum/silanol increased when silanols with an intramolecular hydrogen bond such as the trime

Polymerization of cyclohexene oxide with
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## Abstract The catalytic activity of an aluminum complex/silanol system was found to vary with the aluminum ligand as follows: β‐diketonate < β‐ketoester anion < ortho‐carbonylphenolate. Aluminum complexes with electron donating groups conjugated with a carbonyl group had higher catalytic activity