𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Polymerization of cyclic monomers, 1. Radical polymerization of unsaturated spiro orthocarbonates

✍ Scribed by Norbert Moszner; Frank Zeuner; Volker Rheinberger

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
312 KB
Volume
16
Category
Article
ISSN
1022-1336

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

7‐Methyl‐2‐methylene‐ (1) and 7‐methyl‐2,3‐dimethylene‐1,4,6,9‐tetraoxaspiro[4.4]nonane (2) were synthesized and characterized by elemental analysis, IR, ^1^H NMR and ^13^C NMR spectroscopy. Radical polymerization of the spiro orthocarbonates (SOC) 1 and 2 show that they undergo primarily vinyl polymerization with a low degree of ring‐opening reaction. Homopolymerization of 2 at 120°C with di‐tert‐butyl peroxide gives a transparent crosslinked polymer and the polymerization generates a 12,5% shrinkage in volume.

📜 SIMILAR VOLUMES

Polymerization of cyclic monomers, 2. Sy
Polymerization of cyclic monomers, 2. Synthesis and radical polymerization of vinylcyclopropanes
✍ Frank Zeuner; Norbert Moszner; Volker Rheinberger 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 354 KB

## Abstract New 1,1‐disubstituted 2‐vinylcyclopropanes were synthesized by reaction of the corresponding malonyl diesters with __trans__‐1,4‐dibromo‐2‐butene and of sodium hydride. The structure of the 2‐vinylcyclopropanes could be confirmed by elemental analysis, IR, ^1^H NMR and ^13^C NMR spectro

Polymerization of Cyclic Monomers, 12
Polymerization of Cyclic Monomers, 12
✍ Norbert Moszner; Frank Zeuner; Urs Karl Fischer; Volker Rheinberger; Armin de Me 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 140 KB

## Abstract **Summary:** The radical polymerization of different substituted methyl 2‐(bicyclo[3.1.0]hex‐1‐yl) acrylates, **1a**–**f**, was initiated by 2,2′‐azoisobutyronitrile (AIBN) at 65 °C in chlorobenzene. The radical homopolymerization of **1a**–**f** occurred through the opening of the cycl

Polymerization of Cyclic Monomers, 10,
Polymerization of Cyclic Monomers, 10,
✍ Norbert Moszner; Frank Zeuner; Urs Karl Fischer; Volker Rheinberger; Armin de Me 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB

## Abstract Methyl 2‐(bicyclo[3.1.0]hex‐1‐yl)acrylate (**1**) was synthesized from methyl 2‐(cyclopentene‐1‐yl)‐2‐hydroxyacetate by cyclopropanation, followed by oxidation to the corresponding bicyclic 2‐oxoacetate and Wittig olefination with methyltriphenylphosphonium bromide. Initiated with 2,2′‐

Polymerization of cyclic monomers, 3. Sy
Polymerization of cyclic monomers, 3. Synthesis, radical and cationic polymerization of bicyclic 2-methylene-1,3-dioxepanes
✍ Norbert Moszner; Thomas Völkel; Volker Rheinberger; Elisabeth Klemm 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 636 KB

## Abstract New bicyclic 2‐methylene‐1,3‐dioxepanes, were synthesized starting from 2‐bromomethyl‐5,6‐dihydroxy‐1,3‐dioxepanes. The structure of the 2‐methylene‐1,3‐dioxepanes was confirmed by elemental analysis, IR, ^1^H NMR and ^13^C NMR spectroscopy. Radical polymerization of 2‐methylene‐1,3‐dio

Polymerization of cyclic monomers, 4. Sy
Polymerization of cyclic monomers, 4. Synthesis and radical polymerization of bi- and trifunctional 2-vinylcyclopropanes
✍ Norbert Moszner; Frank Zeuner; Volker Rheinberger 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 271 KB

## Abstract Multifunctional 2‐vinylcyclopropanes were synthesized by esterification of the 1‐methoxycarbonyl‐2‐vinylcyclopropane‐1‐carboxylic acid with ethylene glycol, 1,1,1‐trimethylolpropane or 1,4‐cyclohexanediol in the presence of 1,3‐dicyclohexylcarbodiimide (DCC). The structure of the new vi