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Polymerization of chloroprene with complex catalysts based on butyllithium

✍ Scribed by I.G. Krasnosel'skaya; B.L. Yerusalimskii


Book ID
118358051
Publisher
Elsevier Science
Year
1967
Weight
344 KB
Volume
9
Category
Article
ISSN
0032-3950

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## Abstract The polymerization of styrene by __n__‐butyllithium and titanium tetrachloride has been examined. Isotactic polystyrene is obtained only when 3.00 > __n__‐BuLi/TiCl~4~ > 1.75. At ratios less than 1.75 and greater than 3.00 only amorphous polystyrene (soluble in MEK) was formed. The mole

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Polymerization of isoprene (IP) with alkyllithium (RLi) catalysts in the presence of amines such as triethylamine (TEA), 1,2-dipiperidinoethane (DPPE) and N,N,N@,N@-tetramethyldiaminoalkanes where 4 and 6 (TMDAA)] has been studied. By adding the amines, the polymerization rate of IP was accelerated