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Polymerization of acrylonitrile initiated by the redox system peroxydisulphate-isoamyl alcohol catalyzed by silver ion

✍ Scribed by A. Sarpudeen; I. Tajuddin; Q. Anwaruddin

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 155 KB
Volume: 20
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(84)90088-0

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✦ Synopsis

A~tract--The polymerization of acrylonitrile in aqueous media initiated by peroxydisulphate isoamyl alcohol(IAA) redox pair catalyzed by silver ion was studied at low conversion. The polymerization had kinetic orders 1.5 with respect to monomer, 0.6 (peroxydisulphate) and 0.5 (silver ion). The reactions were carried out at various temperatures and the overall activation energy was found to be 5.5 kcal/mol. The effect of certain water-miscible organic solvents was also investigated. A mechanism of initiation is tentatively proposed.

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