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Polymerization of 4-methylpentadiene-1,3 and the structure of its polymers

✍ Scribed by I.A. Livshits; V.I. Stepanova

Book ID
118357681
Publisher
Elsevier Science
Year
1966
Weight
341 KB
Volume
8
Category
Article
ISSN
0032-3950

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Effect of substituents at position 4 on
Effect of substituents at position 4 on the stereospecific polymerization of 1,3-diolefins. Polymers with a 1,2 isotactic structure from 4-methyl-1,3-pentadiene
✍ L. Porri; M.C. Gallazzi πŸ“‚ Article πŸ“… 1966 πŸ› Elsevier Science 🌐 English βš– 551 KB

Abstraet--4.Methyl-l,3-pentadiene has been polymerized by heterogeneous catalysts from AI(C2Hs) 3 and either TIC14, TIC13 or VCI3, to give polymers having almost exclusively 1,2 units, and showing crystallinity attributable to 1,2 isotactic sequences. Homogeneous systems from AI(C2Hs)3 and either a