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Polymerization of 4-(ferrocenylethynyl)phenylacetylene with transition metal catalysts

✍ Scribed by Jan Sedláček; Jiří Vohlídal; Nikolay Patev; Marta Pacovská; Sandrine Cabioch; Olivier Lavastre; Pierre H. Dixneuf; Hynek Balcar; Pavel Matějka

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
77 KB
Volume
200
Category
Article
ISSN
1022-1352

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Polymerization of N-carbazolylacetylene
Polymerization of N-carbazolylacetylene by various transition metal catalysts and polymer properties
✍ Tomoaki Sata; Ryoji Nomura; Tatsuo Wada; Hiroyuki Sasabe; Toshio Masuda 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 124 KB 👁 2 views

N-Carbazolylacetylene (CzA) was polymerized in the presence of various transition metal catalysts including WCl 6 , MoCl 5 , [Rh(NBD)Cl] 2 , and Fe(acac) 3 to give polymers in good yields. The polymers produced with W catalysts were dark purple solids and soluble in organic solvents such as toluene