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Polymerization of 3-vinylpyrene with Ziegler-Natta catalyst

✍ Scribed by Tanikawa, Kiyoshi ;Kusabayashi, Shigekazu ;Hirata, Hirotaka ;Mikawa, Hiroshi

Publisher
Wiley (John Wiley & Sons)
Year
1968
Tongue
English
Weight
228 KB
Volume
6
Category
Article
ISSN
0449-2986

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Polymerization of 3,5,5-trimethyl-1-hexe
Polymerization of 3,5,5-trimethyl-1-hexene with Ziegler-Natta catalysts
✍ Kiyoshi Endo; Kazuyoshi Fujii; Takayuki Otsu πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 414 KB

## Abstract Polymerization of 3,5,5‐trimethyl‐1‐hexene (TM1H) with TiCI~3~ and alkylaluminium catalysts was studied. TM1H can be polymerized, but the polymerization rate is quite low due to the bulky substituent of the side chain. During the polymerization of TM1H, the isomerization of TM1H to inte