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Polymerization of 3-silyl-1-hexynes and polymer properties

โœ Scribed by Masuda, Toshio; Tsuchihara, Kenji; Ohmameuda, Koji; Higashimura, Toshinobu


Book ID
126398342
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
764 KB
Volume
22
Category
Article
ISSN
0024-9297

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Polymerization and polymer properties of 1-phenyl-2-[4-(triphenylsilyl)phenyl]acetylene (pPh 3 SiDPA) and 1-phenyl-2-[4-(triisopropylsilyl)phenyl]acetylene (piPr 3 SiDPA), which have very bulky silyl groups, were examined. These monomers polymerized in good yields in the presence of TaCl 5 -based ca