Polymerization in microemulsions with metallosurfactants
✍ Scribed by Markus Antonietti; Thomas Nestl
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 270 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1022-1336
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📜 SIMILAR VOLUMES
## Abstract Nitroxide‐mediated polymerizations of styrene in microemulsion have been carried out at 125 °C using the cationic surfactant tetradecyltrimethylammonium bromide and the nitroxides 2,2,6,6‐tetramethylpiperidinyl‐1‐oxy (TEMPO) and __N__‐__tert__‐butyl‐__N__‐[1‐diethylphosphono‐(2,2‐dimeth
Butyl acrylate was initiated with KPS or BPO to polymerize at high monomer concentration in the microemulsions with SBOA (sodium 12-butinoyloxy-9-octadecenate) as emulsifier. The microemulsion remained clear or reddish. It was found that the constant polymerization period appeared in most microemuls