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Polymerization filling of polycaprolactam

✍ Scribed by V.M. Cheshkov; M.M. Natova; N.R. Ashurov; M.M. Usmanova; A.M. Veksel'man

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 285 KB
Volume: 27
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(91)90224-c

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✦ Synopsis

The paper considers the possibility of synthesizing polycaprolactam on the basis of acid-base interaction of the caprolactam with a filler surface (calcium phosphate), without using initiating systems. The surface acidic properties of the filler are estimated by using the method of butylamine titration. Polymerization kinetics are studied and the apparent activation energy of the process, as well as the degree of crystallinity of the resulting polymer, are measured.

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