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Polymeric Salphen-phthalocyanine dinuclear metal complexes for activation of molecular oxygen

✍ Scribed by Rong-Min Wang; Er-Xia Hao; Guo-Rui Shen; Yu-Feng He; Zi-Qiang Lei

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
735 KB
Volume
111
Category
Article
ISSN
0021-8995

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✦ Synopsis

Abstract

The polymeric Salphen Schiff base‐phthalocyanine Co‐Cu dinuclear metal complex (PSalphenCo‐PcCu) was designed and synthesized through interfacial condensation polymerization. The new sheet polymeric dinuclear metal complex has been characterized by IR spectra, UV‐visible spectra, scanning electron microscopy with energy dispersive X‐ray analysis and thermogravimetry analysis. Its catalytic activity for activation of molecular oxygen was investigated by using cumene as substrate without any additive in mild condition. The aerobic oxidation of cumene catalyzed by PSalphenCo‐PcCu proved to be a simple and efficient method for obtaining cumene hydroperoxide in a high selectivity. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009

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