Polymeric Octamolybdate Ions in the Crystal Structure of (NH4)6Mo8O27·4H2O
✍ Scribed by Irene Böschen; Dr. Bruno Buss; Prof. Dr. Bernt Krebs; Prof. Dr. Oskar Glemser
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 129 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
clophane['l o ] (Verzerrung der Benzolringe, extrem kurze H ... H-Abstande) nicht Ursache, sondern Folge der transannularen K-n-Wechselwirkung sind.
NH 4 ) 2 [Mo 6 Cl 14 ] ´H2 O (1) was prepared from reactions of MoCl 2 in ethanol with aqueous NH 4 Cl solution. It crystallizes in the monoclinic space group I2/a (no. 15), Z = 4 with a = 912.3(1), b = 1491.2(2), c = 1724.8(2) pm, b = 92.25(1)°; R1 = 0.023 (based on F values) and wR2 = 0.059 (based
Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space