Polymeric di-n-butyl(glutarato)tin(IV)
✍ Scribed by Ramirez, Alejandro R. ;Parvez, Masood ;Ahmad, Viqar Uddin ;Hussain, Javid ;Hussain, Hidayat
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 279 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Sn(C 4 H 9 ) 2 (C 3 H 6 NS 2 )Cl], the Sn IV atom has a distorted trigonal bipyramidal geometry that is defined by Cl, two S and two C atoms. The dithiocarbamate chelates to the Sn atom in an anisobidentate manner, and the double-bonded S atom occupies one of the two axial si
Values of coupling constants )2J("9Sn, 'H)), determined from 'H NMR spectra, gave estimates of C-Sn-C angles in Me,SnL in the range 128-136 O in methanol and aqueous solutions, which correspond to values from Il9Sn Mossbauer AE parameters (129.6-133.8 "). The structural relationship of R2SnL molecul