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Polymer-Supported Organotin Reagents in the Catalytic Stille Reaction.

✍ Scribed by Alejandro G. Hernan; Vincent Guillot; Alexander Kuvshinov; Jeremy D. Kilburn

Publisher
John Wiley and Sons
Year
2004
Weight
106 KB
Volume
35
Category
Article
ISSN
0931-7597

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## A series of polymer-supported RCpCpTiC12 (Cp = $ -C,H,; RCp = 7 7 ' -RC,H,) has been prepared and reduced by i-C,H,MgBr in situ, then used as catalysts in hydrogenation of styrene, isomerization of 1 ,S-cyclooctadiene and l,S-hexadiene, and reduction of carbonyl compounds. In some cases, the i