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Polymer-supported molybdenum and vanadium catalysts for epoxidation of alkenes by alkyl hydroperoxides

✍ Scribed by R. T. Stamenova; C. B. Tsvetanov; K. G. Vassilev; S. K. Tanielyan; S. K. Ivanov


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
482 KB
Volume
42
Category
Article
ISSN
0021-8995

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The Titanium(IV)-Catalyzed Epoxidation o
✍ Dr. Richard D. Oldroyd; Prof. John Meurig Thomas; Dr. Thomas Maschmeyer; Philip πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 969 KB

A high catalytic activity towards alkene epoxidation is shown by titanium‐modified MCM41 mesoporous silicas if 2‐methyl‐1‐phenyl‐2‐propyl hydroperoxide (MPPH) is used as oxidant. This first example in which MPPH has been used as an efficient two‐electron oxidizing agent demonstrates that it is a com