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Polymer-supported half-titanocene catalysts for the syndiospecific polymerization of styrene

✍ Scribed by Junting Xu; Jianying Ouyang; Zhiqiang Fan; Dequan Chen; Linxian Feng


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
90 KB
Volume
38
Category
Article
ISSN
0887-624X

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Polymer-supported half-titanocene cataly
✍ Junting Xu; Jianying Ouyang; Zhiqiang Fan; Dequan Chen; Linxian Feng πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 168 KB

Monocyclopendienyltitanium trichloride (CpTiCl 3 ) was supported on polymer carriers with different hydroxyl contents, and the supported catalysts were used for styrene polymerization. The supported catalysts exhibited high activity even at low Al/Ti ratios and increased the molecular weight of the

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Poly(styrene-co-acrylamide)(PSAm)-titanium complexes (PSAm \* Ti) were prepared and characterized. It is found that the coordination number of acrylamide (Am) to T i in the complexes is strongly dependent on Am content in PSAm, but not on [Am]/[Ti] ratio in the feed. The infrared and x-ray photoelec