✦ LIBER ✦

Polymer Rings and Chains Consisting of Doubly Silyl-Bridged Metallocenes

✍ Scribed by Frank H. Köhler; Andreas Schell; Bernd Weber

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 43 KB
Volume: 8
Category: Article
ISSN: 0947-6539
DOI: 10.1002/1521-3765(20021216)8:24<5519::aid-chem5519>3.0.co;2-s

No coin nor oath required. For personal study only.

✦ Synopsis

The design of ligands with units that play the role of both antenna and shield leads to highly luminescent complexes (see scheme) for all lanthanides that emit in the visible region.

📜 SIMILAR VOLUMES

Polymer Rings and Chains Consisting of D

Polymer Rings and Chains Consisting of Doubly Silyl-Bridged Metallocenes

✍ Frank H. Köhler; Andreas Schell; Bernd Weber 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB

With the formation of novel organometallic macromolecules in mind, the polycondensation of transition metal ions and bridged cyclopentadienyl ligands was studied. To this end solvated salts MX2 (M = Fe, Ni, and Cr) were treated with a ligand that consisted of two doubly silyl-bridged cyclopentadieny