Polymer protected reagents: (II) Esterifications with P- AlCl3
β Scribed by E.C. Blossey; L.M. Turner; D.C. Neckers
- Book ID
- 104247181
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 190 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In a recent communication from our laboratories, the advantageous use of a polymer protected reagent, polymer protected anhydrous aluminum chloride ( @-AlC19) was reported.3'4
This polymer protected reagent, a tightly bound complex between anhydrous aluminum chloride and polystyrene-divinylbenzene copolymer beads, was described as a polymer protected dehydrating agent which could be released from the polymer by placing it in appropriate swelling solvents.
As part of a general program designed to investigate reactions of polymer protected anhydrous reagents, we report studies of P -A1C135
π SIMILAR VOLUMES
Crosslinked poly(4-vinylpyridine-co-styrene) was prepared and functionalized with titanium tetrachloride to afford the corresponding poly(4-vinylpyridineco-styrene) -titanium tetrachloride complex. This insoluble functionalized polymersupported catalyst shows good catalytic activity for esterificati