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πŸ“

Polymer Networks: Structure and Mechanical Properties

✍ Scribed by M. Gordon, T. C. Ward, R. S. Whitney (auth.), A. J. Chompff, S. Newman (eds.)


Publisher
Springer US
Year
1971
Tongue
English
Leaves
494
Edition
1
Category
Library

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✦ Synopsis


For several decades, polymer science has sought to rationalize the mechanical and thermodynamic properties of polymer networks largely within the framework of statistical thermodynamics. Much of this effort has been directed toward the rubbery rather than the glassy state. It is generally assumed that networks possess an avΒ­ erage composition to which average properties may be assigned; from such a continuum view, a powerful analysis of such properties as modulus, swelling, birefringence and thermoelasticity has emerged. In the years following the rise of polymer characterization (the late 40's and early 50's), many scientists began to study apΒ­ parent relations between the properties of linear polymer molecules and the networks obtainable therefrom. This search was also stimuΒ­ lated by the wide range of applications of polymer networks in comΒ­ mercial elastomers, thermosets and coatings. Frequently, these data were confidently matched with curves obtained from statistiΒ­ cally describable models of networks of ghost chains, uniformly distributed in space. More recently, it has become apparent that polymer chains in networks are not as ideal as assumed in the formulation of statisΒ­ tical models, and there has been a shift in emphasis towards the less than ideal, perturbed and possibly inhomogeneous networks which are more frequently encountered in practice. The continuum approach, however, had to be developed before inhomogeneous systems could be described; the present volume, therefore, contains both views.

✦ Table of Contents


Front Matter....Pages i-xiv
Chemical and Physical Aspects of the Three Stages in Forming Polymer Networks....Pages 1-21
On the Thermostatic Behavior of Elastomers....Pages 23-45
Thermoelasticity of Crosslinked Rubber Networks....Pages 47-56
The Micromechanics of Elastomer Networks....Pages 57-82
The Statistical Mechanics of Rubbers....Pages 83-110
The Rupture Work of Crosslinked Polymers....Pages 111-119
Intermolecular Forces in Polymers and Liquids....Pages 121-143
Glass Points of Polymer Networks....Pages 145-192
The Interaction between Polymeric Structure, Deformation and Fracture....Pages 193-218
Properties of a Highly Crosslinked Elastomer....Pages 219-243
Inhomogeneities Induced by Crosslinking in the Course of Crosslinking Copolymerization....Pages 245-260
The Swelling of Nonuniformly Crosslinked Polymers in Solvents....Pages 261-272
Birefringence Analysis of Inhomogeneous Swelling in Filled Elastomers....Pages 273-291
Depolarized Light Scattering from Swollen-Filled Rubber....Pages 293-305
Light Scattering as a Tool in the Characterization of Polymer Materials....Pages 307-322
Light Scattering by Polymer Networks....Pages 323-339
The Stress-Strain Behavior of Mechanically Degradable Polymers....Pages 341-394
A Constitutive Representation of Inhomogeneous Polymeric Systems....Pages 395-407
Molecular Bond Rupture Associated with Inelastic Deformation of Elastomers....Pages 409-434
Morphology and Mechanical Behavior of Interpenetrating Polymer Networks....Pages 435-450
Synthesis and Properties of Interpenetrating Polymer Networks....Pages 451-452
Chemical Effects on the Ultimate Properties of Polymer Networks in the Glassy State....Pages 453-477
Back Matter....Pages 479-493

✦ Subjects


Polymer Sciences


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