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Polymer network of fixed topology in a high-molecular weight solvent

✍ Scribed by M. Benhamou; A. Bensafi; M. Benmouna


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
766 KB
Volume
107
Category
Article
ISSN
0167-7322

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Some low-molecular-weight polymers (poly(butyl methacrylate), nylon 6, nylon 12) in the solvent system m-cresol/n-heptane, with effective refractive index increments (dn/cac), in the range 0.34~).81 ml/g, have been studied by light scattering. These extremely large values, measured by differential r

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The behaviour of ultra-high molecular weight poly(butyl methacrylate) (/~w = 9.59 Γ— 106-24.50 Γ— 106) in dilute solution in methyl ethyl ketone, benzene, dioxane, and cyclohexanone, at 25c'C. has been investigated by viscometry. Mark Houwink relations have been established, and the unperturbed dimens