Molecular weight distribution has been investigated for polycaproamide obtained in lowtemperature, anionic polymerization of caprolactam in the presence of the sodium salt of caprolactam and carbon dioxide in solvent; fractionation has been performed at 25 Β° using phenol-tetrachloroethane as solvent
Polymer molecular weight in anionic polymerization of caprolactam
β Scribed by V.N. Mikheyev
- Book ID
- 118360252
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 311 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0032-3950
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π SIMILAR VOLUMES
A~tntct--Molecular weight of polycaproamide obtained by anionic polymerization of caprolactam in solution in the presence of sodium caprolactam and carbon dioxide has been investigated by absolute methods. Number average molecular weights were determined by osmometry. Weight average molecular weight
Measurement has been made of the dependence of the molecular weight distribution on the ratio of the catalytic system components and on the polymerization time for polycaprolactam obtained by anionic polymerization. A bimodal character of the curves was observed for products made using molar ratios
At temperatures around 200 ~, condensation and cleavage reactions occur with polymerization, leading to a change in the number of macromolecules. The final number of polymer molecules (A r) depends on the balance between these reactions, their relative rates being affected, in particular, by the con