Polymer-modified electrodes: Part V. The use of hydrodynamically modulated rotating-disk electrodes in the study of the mediated oxidation of [Fe(CN)6]4− at ruthenium-containing polymer-modified electrodes

Mechanism of mediation of the electroche

Mechanism of mediation of the electrochemical oxidation of K4Fe(CN)6 at poly-[tris(3-{ω-[4-(2,2′-bipyridyl)] alkyl}-thiophene)iron(II)]-film modified electrodes in aqueous solutions

✍ Jiaxiong Wang; F.Richard Keene 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 830 KB

The kinetics of the electrochemical oxidation of K,Fe(CN), at poly- [tris(3-{o-[4-(2,2'-bipyridyl)]alkyl}thiophene)iron(II)]-film modified electrodes have been investigated in aqueous solutions, using cyclic voltammetry and rotating disk electrode voltammetry. The retro-electrocatalytic reaction of