In methyl acrylate-or acrylonitrile-grafted northern softwood Kraft or southern softwood Kraft pulp fibers, polymer grafts are present almost homogeneously throughout the fiber wall, although some surface enhancement is observed. On unhydrolyzed fiber surfaces, acrylonitrile grafts protrude in clump
Polymer-grafted cellulose fibers. III. Interactions of grafted and ungrafted fibers in handsheets
β Scribed by R. R. Warner; E. Rezai
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 371 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
In addition to enhanced absorbency, handsheets incorporating hydrolyzed methyl-acrylate-grafted (HMAG) Kraft fibers exhibit enhanced tensile strength and stretchability [E. Rezai and R. R. Warner, J. Appl. Polym. Sci., 00, 000 (19XX)]. These handsheets have a unique morphology. In a handsheet, grafted fibers form stretched planar sheets that appear to bond with neighboring ungrafted fibers. This meshwork of interwoven, stretched cellulose/polymer sheets bonding with normal ungrafted fibers likely accounts for the enhanced tensile strength and stretchability of HMAG-containing handsheets. Analytical electron microscopy is shown to be a useful technique for investigating polymer-grafted fibers in handsheets.
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