Polymer Electrolytes for Energy Storage Devices

✍ Scribed by Prasanth Raghavan (editor), Jabeen Fatima M. J. (editor)

• Publisher: CRC Press
• Year: 2021
• Tongue: English
• Leaves: 303
• Edition: 1
• Category: Library

✦ Synopsis

Polymer Electrolytes for Energy Storage Devices, Volume I, offers a detailed explanation of recent progress and challenges in polymer electrolyte research for energy storage devices. The influence of these electrolyte properties on the performance of different energy storage devices is discussed in detail.

Features:

• Discusses a variety of energy storage systems and their workings and a detailed history of LIBs • Covers a wide range of polymer-based electrolytes including PVdF, PVdF-co-HFP, PAN, blend polymeric systems, composite polymeric systems, and polymer ionic liquid gel electrolytes

• Provides a comprehensive review of biopolymer electrolytes for energy storage applications

• Suitable for readers with experience in batteries as well as newcomers to the field

This book will be invaluable to researchers and engineers working on the development of next-generation energy storage devices, including materials, chemical, electrical, and mechanical engineers, as well as those involved in related disciplines.

✦ Table of Contents

Cover
Half Title
Title Page
Copyright Page
Dedication Page
Table of Contents
Foreword
Editors
Contributors
Abbreviations
Chapter 1 Electrochemical Energy Storage Systems: The State-of-the-Art Energy Technologies
1.1 Introduction
1.2 Types of Electrochemical Energy Storage Devices
1.3 Batteries and Their Classification
1.3.1 Primary (Non-Rechargeable) Batteries
1.3.1.1 Types of Primary Batteries
1.3.2 Secondary (Rechargeable) Batteries
1.3.2.1 Lead-Acid Batteries
1.3.2.2 Nickel-Cadmium Batteries
1.3.2.3 Ni-Metal Hydride Batteries
1.3.2.4 Lithium-Ion Batteries
1.3.2.5 Magnesium-Ion Batteries
1.3.2.6 Fluoride-Ion Batteries
1.3.2.7 Sodium-Ion Batteries
1.3.2.8 Ion-Ion Batteries
1.4 Principles and Types of Lithium-Ion Batteries
1.4.1 Lithium Iodide Battery
1.4.2 Lithium Air Battery
1.4.3 Lithium Redox Flow Battery
1.4.4 Lithium Sulfur Battery
1.5 Supercapacitors
1.6 Fuel Cells
1.6.1 Basic Structure of Fuel Cell
1.6.2 Classification of Fuel Cells
1.6.2.1 Polymeric Electrolyte Membrane Fuel Cells (PEMFC
1.6.2.2 Direct Methanol Fuel Cells (DMFCs
1.6.2.3 Alkaline Fuel Cells (AFCs
1.6.2.4 Phosphoric Acid Fuel Cell (PAFC
1.6.2.5 Molten Carbonate Fuel Cells (MCFC
1.6.2.6 Microbial Fuel Cells (MFC
1.7 Conclusion
Acknowledgment
References
Chapter 2 The Great Nobel Prize History of Lithium-Ion Batteries: The New Era of Electrochemical Energy Storage Solutions
2.1 Introduction
2.2 Development of Energy Storage Devices
2.3 Classification of Batteries
2.4 History of Lithium-Ion Batteries
2.5 Structure of Lithium-Ion Batteries
2.6 Principle of Lithium-Ion Batteries
2.7 Other Types of Battery Based on Lithium-Ion Technology
2.8 Challenges of Next-generation Lithium-Ion Batteries
2.9 The Nobel Prize: The New Era of Lithium-Ion Batteries
2.9.1 Prof. John Bannister Goodenough
2.9.2 Prof. Michael Stanley Whittingham
2.9.3 Prof. Akira Yoshino
2.10 The Draper Prize and Lithium-Ion Battery (2014
2.10.1 Prof. Rachid Yazami
2.10.2 Mr. Yoshio Nishi
2.11 Summary
Acknowledgment
References
Chapter 3 Polyethylene Oxide (PEO)-Based Solid Polymer Electrolytes for Rechargeable Lithium-Ion Batteries
3.1 Introduction
3.2 Preparation of PEO-Based Solid Polymer Electrolytes
3.3 Copolymer-Based PEO Solid Polymer Electrolytes
3.4 Conclusions
Acknowledgment
References
Chapter 4 Polymer Nanocomposite-Based Solid Electrolytes for Lithium-Ion Batteries
4.1 Introduction
4.2 Active Ceramic Filler-Based PNSEs
4.2.1 Garnet-Type Ceramic Fillers for PNSEs
4.2.2 NASICON-Type Ceramic Fillers for PNSEs
4.2.3 Perovskite-Type Ceramic Fillers for PNSEs
4.2.4 Anti-Perovskite-Type Ceramic Fillers for PNSEs
4.2.5 Sulfide-Type Ceramic Fillers for PNSEs
4.3 Inactive Ceramic Oxide-Based PNSEs
4.4 Metal-Organic Frameworks (MOFs) as Fillers for PNSEs
4.5 Biopolymers as Fillers for PNSEs
4.5.1 Cellulose
4.5.2 Chitosan
4.5.3 Proteins
4.5.4 Starch
4.6 Conclusions and Future Perspectives
References
Chapter 5 Poly(Vinylidene Fluoride) (PVdF)-Based Polymer Electrolytes for Lithium-Ion Batteries
5.1 Introduction
5.2 Structure and Ionic Interactions with Lithium Ions
5.3 Methods of Preparation of PVdF-Based Electrolytes
5.3.1 Solvent Casting
5.3.2 Phase Inversion
5.3.3 Electrospinning
5.4 Conclusion
Acknowledgment
References
Chapter 6 Poly(Vinylidene Fluoride-co-Hexafluoropropylene) (PVdF-co-HFP)-Based Gel Polymer Electrolyte for Lithium-Ion Batteries
6.1 Introduction
6.1.1 Crystal Phases of PVdF-co-HFP
6.2 Preparation of PVdF-co-HFP-Based Polymer Electrolytes
6.2.1 PVdF-co-HFP-Based Electrolytes Prepared by Solution Casting
6.2.1.1 Pure PVdF-co-HFP-Based Polymer Electrolytes
6.2.1.2 PVdF-co-HFP-Based Polymer Blend Electrolytes
6.2.1.3 PVdF-co-HFP-Based Ceramic Filler Composite
Polymer Electrolytes
6.2.2 Preparation of PVdF-co-HFP-Based Polymer Electrolytes by
Phase Inversion
6.2.2.1 Pure PVdF-co-HFP-Based Polymer Electrolytes
6.2.2.2 PVdF-co-HFP-Based Polymer Blend Electrolytes
6.2.2.3 PVdF-co-HFP Ceramic Composite Electrolytes
6.2.3 PVdF-co-HFP-Based Polymer Electrolytes Prepared by
Electrospinning
6.3 Conclusion
Acknowledgment
References
Chapter 7 Polyacrylonitrile (PAN)-Based Polymer Electrolyte for Lithium-Ion Batteries
7.1 Introduction
7.2 Mechanism of Ionic Conductivity in Polyacrylonitrile-Based Polymer
Electrolytes
7.3 Methods of Preparation of Polyacrylonitrile-Based Polymer Electrolytes
7.3.1 Polyacrylonitrile-Based Gel Polymer Electrolytes Prepared by
Solvent Casting
7.3.2 Polyacrylonitrile-Based Polymer Electrolytes Prepared by Phase
Inversion
7.3.3 Polyacrylonitrile-Based Polymer Electrolytes Prepared by
Electrospinning
7.4 Polyacrylonitrile-Based Polymer Blend Electrolytes
7.5 Polyacrylonitrile-Based Ceramic Composite Polymer Electrolytes
7.6 Conclusion
Acknowledgment
References
Chapter 8 Polymer Blend Electrolytes for High-Performance Lithium-Ion Batteries
8.1 Introduction
8.2 Polymer Blend Electrolytes
8.2.1 PVdF and PVdF-co-HFP-Based Polymer Blend Electrolytes
8.2.2 Polymethyl Methacrylate (PMMA Based) Polymer Blend
Electrolytes
8.2.2.1 Polymethyl Methacrylate (PMMA Based) Polymer
Blend Electrolytes by Solvent Casting
8.2.2.2 Polymethyl Methacrylate (PMMA Based) Polymer
Blend Electrolytes by Phase Inversion
8.2.2.3 PMMA Based Polymer Blend Electrolytes by
Electrospinning
8.2.3 Polyethylene Oxide (PEO Based) Polymer Blend Electrolytes
8.2.3.1 Polyethylene Oxide (PEO)-Based Polymer Blend
Electrolytes by Phase Inversion
8.2.3.2 Polyethylene Oxide (PEO Based) Polymer Blend
Electrolytes by Electrospinning
8.2.4 Polyvinyl Chloride (PVC Based) Polymer Blend Electrolytes
8.2.4.1 Polyvinyl Chloride (PVC Based) Polymer Blend
Electrolyte by Solvent Casting
8.2.4.2 Polyvinyl Chloride (PVC Based) Polymer Blend
Electrolyte by Electrospinning
8.3 Conclusion
Acknowledgment
References
Chapter 9 Polymer Clay Nanocomposite Electrolytes for Lithium-Ion Batteries
9.1 Introduction
9.2 Ion Transport in Polymer/Clay Nanocomposites
9.3 Polyvinylidene Difluoride (PVdF)-Clay Composite Polymer Electrolytes
9.4 PVdF-co-HFP/Clay Composite Polymer Electrolytes
9.5 Polyacrylonitrile/Clay Composite Polymer Electrolytes
9.6 Polymethyl Methacrylate/Clay Composite Polymer Electrolytes
9.7 Conclusion
Acknowledgment
References
Chapter 10 Polymer Silica Nanocomposite Gel Electrolytes for Lithium-Ion Batteries
10.1 Lithium-Ion Batteries (LIB): A Brief Introduction
10.2 Gel Polymer Electrolytes for Lithium-Ion Batteries
10.3 Silica-Based Gel Polymer Electrolytes for Lithium-Ion Batteries
10.3.1 Fumed Silica-Based Gel Polymer Electrolytes
10.3.2 Nanosilica-Based Gel Polymer Electrolytes
10.3.3 In-Situ-Generated Silica-Based Gel Polymer Electrolytes
10.3.4 Surface-Modified (Functionalized) Silica-Based Gel Polymer
Electrolytes
10.4 Conclusion
Acknowledgment
References
Chapter 11 Polymer-Ionic Liquid Gel Electrolytes for Lithium-Ion Batteries
11.1 Introduction
11.2 Properties of Polymer-Ionic Liquid Gel Electrolytes (PILGEs
11.3 Types of Polymer-Ionic Liquid Gel Electrolytes (PILGEs
11.4 Conclusion and Future Perspectives
References
Chapter 12 Biopolymer Electrolytes for Energy Storage Applications
12.1 Introduction
12.2 Polymer Electrolytes and Their Classifications
12.2.1 Solvent-Free Polymer Salt Complexes
12.2.2 Polyelectrolytes
12.2.3 Gel Polymer Electrolytes
12.2.4 Composite Polymer Electrolytes
12.3 Characteristics of the Polymer Electrolyte
12.4 Biopolymer-Based Polymer Electrolytes and Their Properties
12.4.1 Chitosan-Based Polymer Electrolytes
12.4.2 Starch-Based Polymer Electrolytes
12.4.3 Carrageenan-Based Polymer Electrolytes
12.5 Biopolymer-Based Electrolytes in Lithium Batteries
12.6 Biopolymer-Based Electrolytes for Supercapacitors
12.7 Biopolymer-Based Electrolytes for Fuel Cells
12.8 Conclusion
References
Index