✦ LIBER ✦

Polymer degradation by elimination—IV: Length-distribution of sequences formed during elimination

✍ Scribed by T. Kelen; G. Galambos; F. Tüd″os; G. Bálint

Book ID: 103071129
Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 587 KB
Volume: 6
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(70)90147-3

No coin nor oath required. For personal study only.

✦ Synopsis

The length-distribution of sequences formed from reacted and unreacted monomer units during reaction has been discussed on the basis of the scheme developed for this process. In the case of poly(vinyl chloride), the reacted units are polyenes. The dependence of sequence distribution on conversion and conditional probabilities has been derived. The effect of elimination parameters (,c and 8) on the time-dependence of the distribution function of sequences has been illustrated by some typical examples.

📜 SIMILAR VOLUMES

Polymer degradation by elimination—II. T

Polymer degradation by elimination—II. The probability—theoretical treatment of the elimination assuming a priori given polymer sequences

✍ T. Kelen; G. Galambos; F. Tüdo&#x030B;s; G. Bálint 📂 Article 📅 1969 🏛 Elsevier Science 🌐 English ⚖ 455 KB

A~tract--The treatment of the model concerning the thermal degradation of PVC based upon the probability theory has been performed with the assumption of particular polymer sequences. The treatment has been extended to both the case of no limitations being made to the values of the rate constants an