A multiobjective optimization technique has been developed for free radical bulk polymerization reactors using genetic algorithm. The polymerization of methyl methacrylate in a batch reactor has been studied as an example. The two objective functions which are minimized are the total reaction time a
Polymer Covalent Functionalization of Carbon Nanohorns Using Bulk Free Radical Polymerization
✍ Scribed by Grigoris Mountrichas; Stergios Pispas; Toshinari Ichihasi; Masako Yudasaka; Sumio Iijima; Nikos Tagmatarchis
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 638 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Herein, we report on a facile approach for the covalent functionalization of carbon nanohorns, using in situ bulk free radical polymerization of methacrylic acid. The obtained material is soluble in aqueous media, facilitating its processability and has been fully characterized by means of complementary spectroscopic techniques, electron microscopy, thermogravimetric analysis, and light scattering. Simultaneously, the material has been used as a template for the synthesis of gold nanoparticles on the surface of the polymer‐decorated carbon nanohorns.
📜 SIMILAR VOLUMES
A novel oxazoline-functional methacrylate was prepared and employed as comonomer to produce nonaqueous dispersions of oxazoline-functional polymer particles. In nonaqueous free radical dispersion copolymerization of methylmethacrylate in the presence of oxazoline-functional methacrylate, ethylenegly
## Abstract In this communication we report the synthesis and the efficient polymerization of a PPV trimer, 4‐__tert__‐buty1‐4′‐(4‐vinylstyryl)‐__trans__‐stilbene. By using the TEMPO (2,2,6,6‐tetramethylpiperidin‐1‐yloxy)‐mediated free‐radical polymerization method, the corresponding polymer was ob
## Abstract Previously obtained experimental conversion‐dependences of the propagation rate coefficient (__k__~p~), the termination rate coefficient (__k__~t~) and the initiator efficiency (__f__) for the free‐radical bulk polymerization of styrene at 70 °C have been used to simulate the full molec