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Polymer cosolvent system—II. Preferential adsorption of binary solvent acetone/cyclohexane by poly(p-tert-butylphenyl methacrylate)

✍ Scribed by L. Gargallo; D. Radic; I.A. Katime


Book ID
107753771
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
217 KB
Volume
17
Category
Article
ISSN
0014-3057

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Polymer co-solvent systems—I: Viscometri
✍ L. Gargallo; D. Radic; I. Katime 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 255 KB

The viscometric behaviour of poly(p-tert-butylphenyl methacrylate) in a binary mixture (acetone/cyclohexane) has been studied. This mixture presents a type of partial co-solvency (synergism) for this polymer: cyciohexane is a 0-solvent at 25 ° and acetone is very poor. The conformational parameter s

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✍ D. Radic; L. Gargallo 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 267 KB

The viscometric behaviour and the preferential solvation of poly(4-tert-butylphenyl methacrylate) (PBPh) in tetrahydrofuran/water mixtures have been studied. The results show that water enhances the solubility of this polymer. The system PBPh-tetrahydrofuran-water was studied in detail for 6 fractio