Poly[[(isonicotinic acid-κN)copper(I)]-μ3-chloro]
✍ Scribed by Chen, Qi ;Feng, Wenjun ;Zheng, Xuefang ;Xu, Yan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 206 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
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catena-Poly[copper(I)--[2-(3-pyridyl)benzimidazolato-2 N:N']]
In the crystal structure of the title compound, [CuI(C 5 H 5 -BrN 2 )] n , the Cu and I atoms form Cu-I polymeric double chains in which each Cu atom is coordinated by three I atoms and one N atom of a 2-amino-5-bromopyridine ligand in a distorted tetrahedral geometry. The chains are linked by N-HÁ
The polymeric structure of the title complex, [Cu(C~7~H~4~ClO~3~)~2~(C~6~H~7~NO)~2~]~__n__~, at 100 (2) K contains two-dimensional sheets parallel to the __ac__ plane. The Cu^II^ atom, lying on an inversion centre, has an octahedral coordination environment. It is bonded in a __trans__-square-planar