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Polyhedral Oligomeric Silsesquioxane Amphiphiles: Isotherm and Brewster Angle Microscopy Studies of Trisilanolisobutyl-POSS at the Air/Water Interface

✍ Scribed by Deng, Jianjun; Hottle, John R.; Polidan, Joseph T.; Kim, Hyong-Jun; Farmer-Creely, Catherine E.; Viers, Brent D.; Esker, Alan R.

Book ID
125512256
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
259 KB
Volume
20
Category
Article
ISSN
0743-7463

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Mixed monolayers of per-6-ammonium-per-6-deoxy-per-O 2 , O 3 -hexyl-b-cyclodextrin (1) and per-O 2 , O 3 -hexanoyl-b-cyclodextrin (2) were studied at the air/water interface by Langmuir balance techniques and Brewster angle microscopy. The mixed monolayers show non-ideal mixing with formation of a 3