Poly(ethylene glycol)-supported copper(II) triazacyclononane: an efficient, recoverable, and recyclable catalyst for the cleavage of a phosphodiester

✍ Scribed by Gian Maria Bonora; Sara Drioli; Fulvia Felluga; Fabrizio Mancin; Paola Rossi; Paolo Scrimin; Paolo Tecilla

• Book ID: 104252685
• Publisher: Elsevier Science
• Year: 2003
• Tongue: French
• Weight: 123 KB
• Volume: 44
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(02)02584-4

✦ Synopsis

Triazacyclononane macrocycle has been linked to the soluble polymer monomethoxy poly(ethyleneglycol) and its copper(II) complex efficiently catalyzes the hydrolysis of a model phosphodiester. The catalyst, easily recovered from the water solution, shows no appreciable loss of activity when recycled up to three times.