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Polyelectrolyte solutions: Counterion condensation and intermolecular interactions

✍ Scribed by Russel, W. B.

Publisher
Wiley (John Wiley & Sons)
Year
1982
Tongue
English
Weight
685 KB
Volume
20
Category
Article
ISSN
0098-1273

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✦ Synopsis

Abstract

This article demonstrates that the neglect of nonlinear effects in the conventional counterion condensation theory for the double layer about a charged cylinder can be significant, especially for phenomena involving intramolecular or intermolecular interactions in dilute solutions. For concentrated solutions the Manning theory derives from a linearized superposition approximation for the potential, in contrast to the cylindrical‐cell model, which explicitly treats interactions within an ordered array of parallel cylinders. A new theory which treats interactions explicitly while permitting disorder in two dimensions is presented, and predictions for the osmotic pressure are compared with those from the Manning and cylindrical‐cell models.

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