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Poly[diaqua­bis[μ-1-(carboxyl­atometh­yl)pyridinium-4-carboxyl­ato-κ2O1:O3]cobalt(II)]

✍ Scribed by Yang, Lin ;Jiang, Ning-Yi ;Chen, Xue-Hui ;Li, Song-Lin


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
305 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Co(C 8 H 6 NO 4 ) 2 (H 2 O) 2 ] n , the Co II ion (site symmetry 1) adopts a distorted octahedral coordination geometry. Neighboring metal ions are bridged by 1-(carboxylatomethyl)pyridinium-3-carboxylate ligands, forming a twodimensional coordination network which is stabilized by O-HÁ Á ÁO hydrogen bonds.


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✍ Miao, Qian ;Hu, Mao-Lin ;Chen, Fan 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 299 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.014 A Ê R factor = 0.117 wR factor = 0.247 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.