Lithium diorganocuprates are now widely used in conjugate additions to a,a-unsaturated car-bony1 compounds' and in coupling reactions with alkyl halides2, allyli~acetates~, and other compounds possessing good leaving groups. Here we report a new reaction of lithium dialkylcuprates which is formally
Polycyclic Compounds. Part V: Reaction of Aminoanthraquinones with α,β-Unsaturated Carbonyl Compounds; Synthesis of Disperse Dyes for Polyester
✍ Scribed by N.R. Ayyangar; R.J. Lahoti; S.R. Otiv; K.V. Srinivasan
- Book ID
- 103550681
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 483 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0143-7208
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Indoles react with a@unsaturated carbonyl compounds in the presence of clay catalysts to give substituted indoles in good yields; in one case a 3-benzyl substituent already present migrated to the 2-position, being displaced by the incoming electrophile, thus confirming that electrophilic substituti