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Polycyclic Aromatic Alkaloids, 8. The Structure of Neocalliactine Acetate — Proof by Total Synthesis

✍ Scribed by Bracher, Franz

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 244 KB
Volume: 1992
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.1992199201199

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✦ Synopsis

Abstract

The pentacyclic compound 1 is prepared in six steps by starting from 5,8‐quinolinedione (7). Its spectral data are in accordance with those of neocalliactine acetate, a derivative or the marine alkaloid calliactine. This represents the first definite confirmation of the structure of neocalliactine acetate.

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