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Polycondensation in a continuous, stirred-tank reactor

✍ Scribed by N.H. Smith; G.A. Sather

Publisher: Elsevier Science
Year: 1965
Tongue: English
Weight: 685 KB
Volume: 20
Category: Article
ISSN: 0009-2509
DOI: 10.1016/0009-2509(65)80039-2

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✦ Synopsis

The purpose of this paper is to analyse transient and steady-state polycondensation in a continuous, stirred-tank reactor as an example of large, complex kinetic systems. The approach used is to effect a partial analytical solution of the exact rate equations supplemented by a numerical solution by digital computer. By dimensional analysis a single dimensionless group is obtained, which is related to the polymer yields and molecular weight distribution for both transient and steady-state operation of an isothermal reactor with constant feed composition.

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