## Abstract PBI‐LiHzS composite membranes were prepared by casting __N,N__'‐DMAc solutions containing PBI and LiHzS, where the LiHzS contents in the membranes were between 2.5 and 10 wt.‐%. LiHzS was obtained by reacting hydrazine sulfate and lithium carbonate in water. PBI‐LiHzS composite membrane
Polybenzimidazoles for High Temperature Fuel Cell Applications
✍ Scribed by Hyoung-Juhn Kim; Seong Jin An; Ju-Yong Kim; Jin Kyoung Moon; Sung Yong Cho; Yeong Chan Eun; Hae-Kwon Yoon; Youngmi Park; Ho-Jin Kweon; Eun-Mi Shin
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 102 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
Summary: Fuel cells were designed for high temperature operations. Poly[2,2′‐(m‐phenylene)‐5,5′‐bibenzimidazole] (PBI) was synthesized in a solution of P~2~O~5~, CH~3~SO~3~H, and CF~3~SO~3~H. The PBI was dissolved in a mixture of CF~3~CO~2~H and H~3~PO~4~ and the solution was used for the preparation of Pt catalyst slurry for membrane electrode assembly. The single cell showed a current density of 280 mA · cm^−2^ at a cell voltage of 0.5 V with feeds of H~2~ and O~2~ at 160 °C and without external humidification.
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## Abstract A series of polybenzimidazoles (PBIs) incorporating main chain pyridine groups were synthesized from the pyridine dicarboxylic acids (2,4‐, 2,5‐, 2,6‐ and 3,5‐) and 3,3′,4,4′‐tetraaminobiphenyl, using polyphosphoric acid (PPA) as both solvent and polycondensation reagent. A novel proces
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