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Polyaza-azulenes. Part 1. Synthesis and reactions of some 2,3,3a,6-tetrahydropyrazolo[3,4-d][1,2]diazepines

โœ Scribed by Frost, Jonathan R.; Streith, Jacques


Book ID
120034291
Publisher
Royal Society of Chemistry
Year
1978
Weight
699 KB
Volume
11
Category
Article
ISSN
1472-7781

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Synthesis of 1,4,5,6-tetrahydropyrazolo[
โœ J. Donald Albright; Xuemei Du ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 434 KB

## Abstract The synthesis of 7,8โ€dihydroโ€5(6__H__)โ€quinolinone (**3**) from commercially available 3โ€aminoโ€2โ€cyclohexenโ€1โ€one (**1**) and 3โ€(dimethylamino)acrolein (**4**) in 23% yield avoids the preparation of propynal (**2**). Conversion of 5โ€(4โ€methylphenylsulfonyl)โ€6,7,8,9โ€tetrahydroโ€5__H__โ€pyr