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Polyampholytes in Advanced Polymer Science and Emerging Technologies

✍ Scribed by Kudaibergenov S.E.


Publisher
CRC Press
Year
2025
Tongue
English
Leaves
307
Series
Emerging Materials and Technologies
Category
Library

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✦ Synopsis


Polyampholytes are unique polymers containing acid/base and/or anionic/cationic groups in the main or side chains. Water-soluble and water-swelling polyampholytes exhibit properties that provide broad potential as structural biomaterials, drug delivery and chemo-mechanical systems, biosensors, energy storage devices, supercapacitors, and actuators, among others. This monograph reviews innovative studies in this field over the past two decades with the aim to analyze and systematize the literature in the context of emerging technologies. • Offers a multidisciplinary perspective covering polyampholytes, polybetaines and polyzwitterions in nanotechnology, biotechnology, medicine, catalysis, environment protection, and oil industry applications.
• Demonstrates a wide range of applications for these materials, with enough depth to provide critical fundamental knowledge for new researchers in the field.
• Discusses polyampholyte-protected and gel-immobilized metal nanoparticles and enzymes that catalyze reactions of hydrolysis, decomposition, hydrogenation, and oxidation of various substrates in batch-type and continuous-flow-type reactors.
• Highlights remaining persistent challenges in the development and application of these materials.
The book will appeal to a readership that conducts materials research for biomedical, water treatment, and environmental remediation applications.

✦ Table of Contents


Cover
Half Title
Emerging Materials and Technologies Series
Polyampholytes in Advanced Polymer Science and Emerging Technologies
Copyright
Dedication
Contents
Introduction
References
Preface
1. Water-Soluble Polyampholytes
1.1 Annealed Polyampholytes
1.2 Quenched Polyampholytes (QPA) or Polyzwitterions
1.3 Polymeric Betaines and/or Polyzwitterions
1.4 Polybetainic (or Polyzwitterionic) Soaps
1.5 Low and Upper Critical Solution Temperatures (LCST and UCST) of Polyampholytes
1.6 Polyampholytic Ionic Liquids
1.7 Semi-Natural Polyampholytes
1.8 Structural and Behavioral Similarity of Synthetic and Natural Polyampholytes and Intrinsically Disordered Proteins (IDPs)
1.9 Polyampholytic Behavior of Interpolyelectrolyte Complexes (IPEC)
References
2. Stimuli-Responsive Properties of Hydrophobically Modifed Polyampholytes (HMPA) in Solution
2.1 Thermo- and pH-Sensitive HMPA
2.2 Solvent-Sensitive HMPA
2.3 Salt-Sensitive HMPA
2.4 Light-Sensitive HMPA
2.5 Langmuir–Blodgett and LbL Films of HMPA
2.6 Solubilization of SWCNT and MWCNT by HMPA
References
3. Stimuli-Responsive Amphoteric Nano-, Micro-, and Macroporous Gels
3.1 Thermo-, pH-, and Solvent-Responsive Gels
3.2 Salt-Responsive Gels
3.3 Electric-Responsive Gels
3.4 Bioresponsive Gels
3.5 Self-Healing and Shape Memory Gels
3.6 Amphoteric Nano-, Micro-, and Macroporous Gels
3.7 Molecularly Imprinted Polyampholyte Gels
References
4. Macromolecular Complexes of Polyampholytes
4.1 Intra- and Interpolyelectrolyte Complexes of Polyampholytes
4.2 Polyampholyte–Polyelectrolyte, Polyampholyte–Protein, and Polyampholyte–DNA Complexes
4.3 Polyampholyte–Metal Complexes
4.4 Polyampholyte–Surfactant Complexes
4.5 Polyampholyte–Dye Complexes
4.6 Stabilization of Metal Nanoparticles by Polyampholytes
4.7 Isoelectric Effect
References
5. Polyampholytes in Biotechnology and Medicine
5.1 Polyampholytes as Protein and Drug Delivery Systems
5.2 Mucoadhesive Properties of Natural and Synthetic Polyampholytes
5.3 Amphoteric Hydrogels as Perspective Structural Biomaterials
5.4 Antifouling and Hemocompatible Polyampholytes
5.5 Cryoprotective Polyampholytes
References
6. Polyampholytes in Catalysis
6.1 Catalysis by Polyampholytes
6.2 Catalysis by Polyampholyte–Metal Complexes
6.3 Polyampholyte-Protected Metal Nanoparticles in Catalysis
6.4 Catalytic Properties of Catalase Immobilized within Polyampholyte Cryogels
References
7. Application of Polyampholytes in Emerging Technologies
7.1 Wastewater Purifcation and Desalination
7.2 Polyampholytes in Enhanced Oil Recovery (EOR)
7.3 Polyampholytes as Additives to Drilling Fluids
7.4 Polyampholytes in Stabilization of Colloid Dispersions
7.5 Polyampholytes in Drag Reduction
7.6 Polyampholytes as Pour Point Depressants
7.7 Application of Polyampholytes in Leather Treatment
7.8 Polyampholyte-Based Supercapacitors and Sensors
7.9 Storage of Information (or Coding) on Amphoteric Macromolecules
References
Conclusion
Index


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