Poly(ammonioalkanesulfonate) Blends with Polar Organic Species and Alkali Metal Salts: Structure, Glass Transition and Ionic Conductivity
✍ Scribed by Monique Galin; Eve Marchal; André Mathis; Jean-Claude Galin
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 195 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1042-7147
No coin nor oath required. For personal study only.
✦ Synopsis
Because the dipole moment of its zwitterionic side group is very high ( ϳ 23 D), poly [3-(N,N-diethyl-N-(5-methacryloyoxy-3-oxopentyl)-ammonio) propanesulfonate] affords a unique polar host matrix possessing a strong solvation power towards a variety of polar or ionic guest species. Water, glycerol, liquid ethylammonium nitrate, triethylammoniopropanesulfonate are all good plasticizers with a fairly similar efficiency of ⌬T g ϳ Ϫ 2°C/mol% of additive, while a dizwitterion behaves as a weak antiplasticizer. The stoichiometric blends of the polyzwitterion with alkali metal salts of low enough lattice energy such as thiocyanates, trifuoromethanesulfonates, iodides, perchlorates, tetrafluoro or tetraphenylborates, are amorphous systems showing a single glass transition, with plasticization or antiplasticization effects depending on the salt nature. Microphase separation systematically occurs in these binary systems but long-range order is observed only in some cases, with development of lamellar (I Ϫ ) or hexagonal (SCN Ϫ ) structures. Conductivity increases and the dielectric constant of the material decreases as salt is added. The activation energies of the conductivity are not strongly affected either by the state of the material, glassy or viscoelastic, or by the salt nature.