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Poly(alkyl itaconate)s. Formation of mixed esters and the properties of the resulting polymers

✍ Scribed by J.M.G. Cowie; M. Yazdani Pedram; R. Ferguson

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 321 KB
Volume: 21
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(85)90224-1

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✦ Synopsis

Methods have been described for the synthesis of derivatives of itaconic acid in which the groups attached to the carboxyl functions are different. A series of mixed esters with alkane sidechains of various length have been prepared from monomethyl itaconate as a precursor and some of the properties of the polymers made from these mixed esters have been measured. To the first approximation, the plasticizing effect of the side chains, resulting in changes in the glass transition temperature (Tg), is proportional to the total number of carbon atoms in both side chains

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