✦ LIBER ✦

Polyaddition of bifunctional spiro orthoesters with bifunctional acid chlorides accompanying double ring-opening isomerization

✍ Scribed by Haruo Nishida; Fumio Sanda; Takeshi Endo; Takeshi Nakahara; Takayuki Ogata; Koshi Kusumoto

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 123 KB
Volume: 38
Category: Article
ISSN: 0887-624X
DOI: 10.1002/(sici)1099-0518(20000101)38:1<68::aid-pola9>3.0.co;2-4

No coin nor oath required. For personal study only.

✦ Synopsis

Polyaddition of bifunctional spiro orthoesters (SOEs) with bifunctional acid chlorides was examined to develop zero-shrinkage polymerization. The polyaddition afforded the corresponding polyether-esters by repeating the addition reaction accompanying the double ring-opening isomerization of the SOE moiety in a manner similar to the reaction of monofunctional SOEs with acid chlorides. The polyaddition accompanied a slight shrinkage or expansion in volume.

📜 SIMILAR VOLUMES

Polyaddition of bifunctional bicyclo ort

Polyaddition of bifunctional bicyclo ortho esters with acid chlorides accompanying double ring-opening isomerization

✍ Haruo Nishida; Fumio Sanda; Takeshi Endo; Takeshi Nakahara; Takayuki Ogata; Kosh 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 53 KB 👁 2 views

Addition reaction of spiro orthoesters w

Addition reaction of spiro orthoesters with electrophiles: A model reaction for the development of novel polyaddition accompanying ring-opening isomerization

✍ Haruo Nishida; Fumio Sanda; Takeshi Endo; Takeshi Nakahara; Takayuki Ogata; Kosh 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 203 KB 👁 2 views

The addition reaction of spiro orthoesters (SOEs) with electrophiles accompanying ring-opening isomerization was investigated as a model reaction for polyaddition of bifunctional SOEs with bifunctional electrophiles. Among several electrophiles such as carboxylic acids and carboxylic anhydrides, aci

Ring-opening isomerization addition reac

Ring-opening isomerization addition reaction of bicyclo ortho esters with acid chlorides. Model reaction for development of a novel polyaddition reaction accompanying ring-opening isomerization

✍ Haruo Nishida; Fumio Sanda; Takeshi Endo; Takeshi Nakahara; Takayuki Ogata; Kosh 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 75 KB 👁 2 views