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Polyacrylic acid production in China


Book ID
114374295
Publisher
Elsevier Science
Year
2003
Weight
31 KB
Volume
2003
Category
Article
ISSN
1351-4210

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High-temperature degradation of polyacry
โœ A. Gurkaynak; F. Tubert; J. Yang; J. Matyas; J. L. Spencer; Carl C. Gryte ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 501 KB

Poly(acry1ic acid) (PAA) was decarboxylated in aqueous solution as a function of pH and ionic strength in the temperature range 10O-35O0C. Degradation kinetics were first order with respect to acid functionality. The rate of decarboxylation at high pH (E, = 51.1 kcall mol) was much slower than that