## Abstract The first successful synthesis of conjugated rod–coil star block copolymer, (PF‐__b__‐P2VP)~__n__~, containing conjugated poly[2,7‐(9,9‐dihexylfluorene)] (PF), and coil‐like poly(2‐vinylpyridine) (P2VP) by combining a Suzuki coupling reaction and living anionic polymerization is reporte
Poly[2,7-(9,9-dihexylfluorene)]-block-poly(2-vinylpyridine) Rod−Coil and Coil−Rod−Coil Block Copolymers: Synthesis, Morphology and Photophysical Properties in Methanol/THF Mixed Solvents
✍ Scribed by Lin, Chia-Hung; Tung, Yi-Chih; Ruokolainen, Janne; Mezzenga, Raffaele; Chen, Wen-Chang
- Book ID
- 111901636
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 828 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0024-9297
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## Abstract **Summary:** The synthesis, morphology, and photophysical properties of PF‐__b__‐PAA with different coil lengths in dilute solutions of dichloromethane/methanol are reported. A tape‐like lamellar morphology is observed at a short coil length of PF‐__b__‐PAA. As the coil length increases
## Abstract Novel luminescent electrospun (ES) fibers have been successfully prepared from a conjugated rod–coil block copolymer, poly[2,7‐(9,9‐dihexylfluorene)]‐__block__‐poly(methyl methacrylate) (PF‐__b__‐PMMA) using a single‐capillary spinneret. Experiment results indicate that PF‐__b__‐PMMA ES