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Poly-(3-Carbethoxypentenamer) in the radical isomerization polymerization of the ethyl ester of 2-vinylcyclopropanecarboxylic acid

✍ Scribed by I.S. Lishanskii; A.G. Zak; Ye.I. Zherebetskaya; A.S. Khachaturov

Book ID
119472439
Publisher
Elsevier Science
Year
1968
Weight
548 KB
Volume
9
Category
Article
ISSN
0032-3950

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The 'H and ISF NMR spectra of the CH,FCHF group in FCH,CHFCO,C,H, were analysed on the basis of an ABCXY spin system. The non-equivalence of the methylene protons is discussed in terms of rotational isomerism. It is concluded that the dominant rotamer is probably considerably distorted from a perfec