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Polarographic Study of the Restriction of the Tautomerism of Amidines by Hydrogen Bonding 1

โœ Scribed by Runner, Mervin E.; Kilpatrick, Mary L.; Wagner, E. C.


Book ID
127178450
Publisher
American Chemical Society
Year
1947
Tongue
English
Weight
582 KB
Volume
69
Category
Article
ISSN
0002-7863

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The 13 C cross-polarization magic angle spinning NMR spectra of N-( ) indicate a keto-hydroxy tautomerism of 1 but not of 2. This was confirmed by a single-crystal x-ray diffraction study of 1, which revealed that the two distinct molecules in the unit cell are linked by intermolecular hydrogen bon