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Polarographic study of the Eu(III)-triethylenetetraaminehexaacetic acid complex and determination of europium by oscillopolarography

✍ Scribed by Xiao-Tai Fu; Chun-Ming Wang; Yu-Xiang Zhang


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
309 KB
Volume
272
Category
Article
ISSN
0003-2670

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✦ Synopsis


The smgle-sweep polarographlc behavlour of Eu(III)-TTHA (tnethylenetetraammehexaacetic acid) complex was studied In 0 1 mol 1-l NH&l + 0 1 mol I-' NH, solution, the electrode reactlon of the complex LS [Eu(III)L13-+ e + ENI) + L6-and the polarograplnc current IS controlled by the diffusion process of the complex The method can be used to determme trace Eu concentrations In the range 2 5 x 10e6-5 0 x 10e4 mol I-' m solution


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NMR study of intramolecular chemical exc
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An intramolecular ligand rearrangement taking place via a bond-breaking process in the lanthanum(III) complex of triethylenetetraaminehexaacetic acid was probed by dynamic NMR experiments. Evidence that the ligands are exchanging derives from the observation of temperature-and mixing time m -depende