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Polarographic study of the complex systems Cu(II)neutral l-isoleucine and Cu(II)lisoleucinate ion

✍ Scribed by V.V. Castro-Aleman; M.T. Sanz-Alaejos; J.C. Rodriguez-Placeres; F.J. Garcia-Montelongo

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
214 KB
Volume
35
Category
Article
ISSN
0013-4686

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✦ Synopsis

The coorchnated systems (Cu(II)-neutral L-lsoleucme and Cu(II)-L-lsoleuanate Ion have been sturhed polarographlcally, m aqueous medmm, p=l OM (NaClO,) and 25kO l"C, and the stability constants of the complexes ICuI1'+ (/311, =23), ICuI,1'+ (&= 180) and JCu(I-),I (jloz= 1 8 10") have been determined

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Determination of the charge of complex s
Determination of the charge of complex species that are reduced at the dme and of the coefficient of transfer, α, in the Cu(II)aq. M citrate (M: Li+, Na+ and K+) system
✍ V. Alvarez; S. González; A. Arévalo 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 299 KB

The minimum presented by the polarograms of the reduction of Cu(I1) in Li+, Na+ and K+ citrate is analysed in order to determine the charge of the reacting species and the coefficient of transfer, OL, of the process. The results obtained allow the participation of thecomplex anions (Cu,Cit,)'-and (C