Polarographic reduction of rubeanic acid and the catalytic waves observed in the presence of ruthenium trichloride
✍ Scribed by J. Hojman; A. Stefanović; B. Stanković; P. Zuman
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 901 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0022-0728
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It is shown theoretically and experimentally that the first catalytic pre-wave in the Ni\*+-NCS-system (the reduction of the [Ni(NC%] complex) at COOS-< (l\*O-1.5) X IO-\* M (cNC#-> twin+) and within a wide range of ionic strength I can be described by a simplified kinetic equation based on the assu
The polarographic catalytic wave of vitamin P in the presence of persulfate was studied by linear potential scan polarography and cyclic voltammetry. Vitamin P yielded a single reduction wave in acidic aqueous solution, which was ascribed to a 2e ؊ , 2H ؉ reduction of the carbonyl group in the C-4 p