✦ LIBER ✦
Polarographic reduction of hexaquo-isothiocyanato-and azido-chromium(III) ions on a dropping mercury electrode in aqueous acid perchlorate solution
✍ Scribed by H. Yamaoka
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 823 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0022-0728
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✦ Synopsis
In Matsuda's treatment 11, only the oxidized form of the reactants is assumed to be initially present in the solution (el ref. 28). This matches with the experimental condition of the present work. ** Matsuda's treatment 11 does not take into account the specific and non-specific adsorption of the reactants. Therefore, the statement above is only qualitative in such a case. In respect to the limited resolution power of the measuring device used in the present work, it is not profitable to employ more rigorous treatments (el. ref. 42).